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http://148.72.244.84:8080/xmlui/handle/xmlui/12578| Title: | [N,N-Etheylene bis (Salicylidene iminato)](benzoyl acetonato) Iron(111) as thermal initiator of methyl methacrylate polymerization |
| Authors: | A.F.Dawood M.A.Ibraheem |
| Issue Date: | 2010 |
| Publisher: | University of Diyala |
| Abstract: | The polymerization of methyl methacrylate(MMA) initiated by a mixed ligand complex , [N,N-Etheylene bis (Salicylidene iminato)](benzoyl acetonato) Iron(111) has been studied in bulk at 80◦C .The rate order of polymerization is 0.5 with respect to initiator concentration and 1.5 with respect to monomer concentration .The activation energy and the kinetic are evaluated .According to the experimental results obtained a free radical mechanism has been proposed |
| URI: | http://148.72.244.84:8080/xmlui/handle/xmlui/12578 |
| ISSN: | 2222-8373 |
| Appears in Collections: | مجلة ديالى للعلوم الاكاديمية / Academic Science Journal (Acad. Sci. J.) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 59-69 E.pdf | 394.67 kB | Adobe PDF | View/Open |
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